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Dondra Biller and Prae Supcharoen,
Woods Hole Oceanographic Institution
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Week 3
17 July 2006


Searching for the Elusive Element Using Chemical Oceanography

Part II


Part II –
Woods Hole Oceanographic Institution Group

 

Oceanographers from Woods Hole Oceanographic Institution are also using chemical tracers to find the source of iron in the Southern Ocean and Southern Scotia Sea.

The Southern Ocean covers about 35,000 square kilometers, or 10% of the World's oceans. Most of the water surrounding Antarctica is around 9,900 feet deep. The Southern Ocean is the only truly global ocean, connecting the Atlantic, Pacific and Indian basins.
Link Link

1. What is the project?

  • We are using radium isotopes as tracers to study the movement of shelf water, which is believed to be a primary source of iron for the Southern Scotia Sea. We will also study thorium as a tracer of particle flux in the upper ocean.

    Isotopes – variants of a chemical element

    Radium, thorium – types of chemical elements

    Flux - flow

Elements_Pics.pdf
Graphical Periodic Table of Elements. Click to download PDF version. pdf
Link Link

 

What do you already know about the topic?

  • In the austral summer of 2005-2006, we conducted a study in this area. Preliminary data show that the shelf water is rapidly transported offshore. Our data correspond with the high iron inventory that the Measures group (University of Hawaii) observed in 2004.

 

What is it you want to learn this time?

  • We hope to better understand the movement of shelf water. Comparison between winter and summer data might help us understand dynamics of shelf water movements. Understanding these water movements will help us further identify the source of iron as a limited nutrient in the study area.

  • Most importantly, this is our first cruise. As graduate students, we have been learning how oceanographers conduct research at sea. Learning about different projects from biological, physical, and chemical oceanographers and seeing them work together as a team are some of the best experiences.. We are really lucky to be part of this cruise on the Palmer, the gigantic floating science laboratory.

 

Ratsirin Supcharoen (Prae), Graduate Student
Massachusetts Institute of Technology/Woods Hole Oceanographic Institution Joint Program - Woods Hole, Massachusetts
Link Biography

 

2. Why do you want to do this?

  • Besides gaining scientific knowledge from our project, we will share and discuss results with other oceanographers. Our collaborative works might reveal some interesting facts about the Southern Ocean’s nature.

 

3. Where are you carrying out the project?
How
is the location important tofinding out what you want to know?

  • The study area is in the southern Drake Passage region, specifically the eastern and the western sides of the Shackleton Transverse Ridge. This location is important since it is a mixing zone between the ACC (Antarctic Circumpolar Current) and the shelf water. These two distinct water masses influence distributions of chemical elements and phytoplankton community in the region.


Drake Passage

The Southern Ocean is dominated by the Antarctic Circumpolar Current (ACC)
LinkLink

Drake Passage
LinkLink

 

4. How are you gathering, processing, and analyzing information?

  • For the radium analysis:

    • First, we collect about 550 liters of water in barrels.
    • Next, we filter seawater through manganese oxide infused acrylic fibers. These fibers will extract all the radium from the sample.
    • Then, we use custom made radiation detectors to measure the activity of radium in fibers.
    • Later, we will use radium activity data to calculate the export flux of the shelf water and associated iron.

Radium is a chemical element, which has the symbol Ra and atomic number 88 (see the periodic table) Image by Daniel Mayer or GreatPatton and released under terms of the GNU FDL

For our thorium analysis:

  • We collect 4 liter bottles of seawater.
  • To this we will add a thorium tracer, certain acids and bases, potassium permanganate and manganese chloride.
  • We filter the solutions and bring the samples back to Woods Hole for the processing and counting of the thorium isotope of interest.
Elements_Pics.pdf
Thorium is a chemical element in the periodic table that has the symbol Th and atomic number 90. As a naturally occurring, slightly radioactive metal, it has been considered as an alternative nuclear fuel to uranium.
Link Link

 

Point of clarification
http://www.nsf.gov/od/opp/antarct/treaty/opp06001/index.jspAs part of the U.S. Antarctic Program, more than 800 researchers and special participants will conduct 165 projects during the 2005–2006 austral summer, with some projects continuing through the austral winter.
NSF U.S. Antarctic Program, 2005–2006

 


Week 3
17 July 2006
Searching for the Elusive Element
Using Chemical Oceanography
Part I – Section I

Part I Section I Part I – Section I

The University of Hawaii Group
Part I – Section II Part I Section II Part ISection II University of Hawaii Group
Chemical Oceanography – 
How Scientists Collect Data on Trace Minerals
Part II Part II Part II Woods Hole Oceanographic Institution Group




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NSF Office of Polar Programs, Antarctic Sciences Section
This special report was made possible by the NSF Office of Polar Programs, Antarctic Sciences Section, Award Nos. ANT04-44134 University of California-San Diego Scripps Institution of Oceanography (B. Gregory Mitchell, Farooq Azam, Katherine Barbeau, Sarah T. Gille, Osmund Holm-Hansen); ANT04-43403 University of Hawaii (Christopher I. Measures, Karen E. Selph); ANT04-44040 University of Massachusetts Boston (Meng Zhou); ANT04-43869 Woods Hole Oceanographic Institution (Matthew A. Charette),  for the study entitled "Collaborative Research: Plankton Community Structure and Iron Distribution in the Southern Drake Passage".